Aluminium hydride is an inorganic compound with the formula AlH3.
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Aluminium hydride is an inorganic compound with the formula AlH3.
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Aluminium hydride, or alane, is a colorless and nonvolatile solid.
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Aluminium hydride is prepared by treating lithium aluminium hydride with aluminium trichloride.
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In organic chemistry, aluminium hydride is mainly used for the reduction of functional groups.
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Aluminium hydride will reduce aldehydes, ketones, carboxylic acids, anhydrides, acid chlorides, esters, and lactones to their corresponding alcohols.
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Likewise, aluminium hydride can accomplish the reduction of an ester in the presence of nitro groups.
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Aluminium hydride can be used in the reduction of acetals to half protected diols.
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Aluminium hydride can be used in epoxide ring opening reaction as shown below.
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Allylic rearrangement reaction carried out using aluminium hydride is a SN2 reaction, and it is not sterically demanding.
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Aluminium hydride will reduce carbon dioxide to methane with heating:.
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