In chemistry, a free radical is an atom, molecule, or ion that has at least one unpaired valence electron.
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In chemistry, a free radical is an atom, molecule, or ion that has at least one unpaired valence electron.
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Notable example of a Free radical is the hydroxyl Free radical, a molecule that has one unpaired electron on the oxygen atom.
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Delocalization of electrons across the structure of a Free radical, known as its ability to form one or more resonance structures, allows for the electron-deficiency to be spread over several atoms, minimizing instability.
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The HOMO of a Free radical is singly-occupied hence the orbital is aptly referred to as the SOMO, or the Singly-Occupied Molecular Orbital.
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The tocopherol Free radical itself is insufficiently stable for isolation, but the parent molecule is a highly effective hydrogen-atom donor.
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Drying oils and alkyd paints harden due to Free radical crosslinking initiated by oxygen from the atmosphere.
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Such reactions cause the depletion of the ozone layer, especially since the chlorine radical is free to engage in another reaction chain; consequently, the use of chlorofluorocarbons as refrigerants has been restricted.
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Radicals are necessary for life, the body has a number of mechanisms to minimize Free radical-induced damage and to repair damage that occurs, such as the enzymes superoxide dismutase, catalase, glutathione peroxidase and glutathione reductase.
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Some symptoms of aging such as atherosclerosis are attributed to Free radical induced oxidation of cholesterol to 7-ketocholesterol.
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Until late in the 20th century the word "Free radical" was used in chemistry to indicate any connected group of atoms, such as a methyl group or a carboxyl, whether it was part of a larger molecule or a molecule on its own.
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Term Free radical was already in use when the now obsolete Free radical theory was developed.
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