Superheated water is stable because of overpressure that raises the boiling point, or by heating it in a sealed vessel with a headspace, where the liquid water is in equilibrium with vapour at the saturated vapor pressure.
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Superheated water is stable because of overpressure that raises the boiling point, or by heating it in a sealed vessel with a headspace, where the liquid water is in equilibrium with vapour at the saturated vapor pressure.
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The extensive hydrogen bonded network in Superheated water tends to oppose this alignment, and the degree of alignment is measured by the relative permittivity.
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Solubility of gases in Superheated water is usually thought to decrease with temperature, but this only occurs to a certain temperature, before increasing again.
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Energy required to heat Superheated water is significantly lower than that needed to vaporize it, for example for steam distillationand the energy is easier to recycle using heat exchangers.
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Extraction using superheated water tends to be fast because diffusion rates increase with temperature.
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Therefore, extraction with superheated water can be both selective and rapid, and has been used to fractionate diesel and woodsmoke particulates.
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Superheated water is being used commercially to extract starch material from marsh mallow root for skincare applicationsand to remove low levels of metals from a high-temperature resistant polymer.
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Analytical purposes, superheated water can replace organic solvents in many applications, for example extraction of PAHs from soilsand can be used on a large scale to remediate contaminated soils, by either extraction alone or extraction linked to supercritical or wet oxidation.
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Several different types of reaction in which Superheated water was behaving as reactant, catalyst and solvent were described by Katritzky et al.
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Superheated water can be used to chemically convert organic material into fuel products.
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The use of Superheated water allows the use of the flame ionisation detector, which gives mass sensitive output for nearly all organic compounds.
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